Chemical Analysis

CHEMICAL ANALYSIS OF SOURCE BQ-2. ANALYTICAL LABORATORY OF NATURAL TREATMENT SOURCES, KARLOVY VARY, CZECH REPUBLIC, 03.19.2014
CATIONS
CationsSignSubstanceSubstanceSubstanceSubstanceMethodNanomole
mg/l-1mmol/l-1mwal/l-1eq%%
Ammonium ionNH4+1,930,110,112,73*10
LithiumLi+0,020,000,000,00*12
SodiumNa+48,52,112,1153,73*10
КалийK+1,20,030,030,78*11
PotassiumCa2+18,20,450,9123,13*12
MagnesiumMg2+9,30,380,7719,49*12
BariumBa2+0,1080,000,000,00*5
StrontiumSr2+0,2370,000,010,14*15
IronFe2+0,150,000,000,00*10
ManganeseMn2+0,050,000,000,00*10
ChromiumCrIII< 0,000 10,000,000,00*
AluminumAl3+0,0010,000,000,00*10
BerylliumBe2+< 0,000 050,000,000,00*
VanadiumV4+< 0,000 10,000,000,00*
CopperCopperCu2+< 0,000 30,000,000,00*
CobaltCo2+< 0,000 050,000,000,00*
CadmiumCd2+< 0,000 020,000,000,00*
LeadPb2+0,000 10,000,000,00*10
NickelNi2+< 0,000 50,000,000,00*
ZincZn2+0,0010,000,000,00*10
SilverAg+< 0,000 050,000,000,00*
MolybdenumMoVI< 0,000 50,000,000,00*
MercuryHgII< 0,000 20,000,000,00*
UranilUO22+< 0,000 10,000,000,00*
CesiumCs+< 0,0010,000,000,00*
RubidiumRb+< 0,0010,000,000,00*
AntimonySbIII< 0,000 10,000,000,00*
TinSn2+< 0,000 50,000,000,00*
Amount of cations:79,703,093,93
ANIONS
AnionSignSubstanceSubstanceSubstanceSubstanceMethodNanomole
mg/l-1mmol/l-1mwal/l-1экв%%
HydrocarbonateHCO32143,513,5185,77*15
FluorideF0,090,000,000,00*15
ХлоридCl20,60,580,5814,21*8
ChlorideBr0,0980,000,000,00*15
IodideI0,1170,000,000,02*15
SulfateSO42-< 1,00,000,000,00*
NitriteNO2< 0,010,000,000,00*
NitrateNO3< 0,500,000,000,00*
HydrophosphateHPO42-0,310,000,000,00*13
HydrosulphateHAsO42-0,001 30,000,000,00*10
SelenideSeO32-< 0,001 60,000,000,00*
*
CyanideCN< 0,0040,000,000,00*
Amount of anions:235,24,094,09100,00
Non-dissociated componentsSubstanceSubstanceMethodNanomole
mg/l-1mmol/l-1%
Boric acid HBO20,8510,02*12
Silicic acid H2SiO316,80,22*15
Non-dissociated components in general:17,70,23
Total mineralization:SubstanceSubstance
mg/l-1mmol/l-1
Total mineralization:3337,4
ORGANIC SUBSTANCES
NEV and surfactant-ASubstanceMethodNanomole
mg/l-1%
Non-polar extractables (NEV)< 0,01*
Anionic surfactants (surfactant)0,032*12
Humic substances< 1,0*
Volatile organic compoundsSubstanceMethodNanomole
mg/l-1
1,1 – asymmetric dichlorethylene (vinylidene chloride; vinylidene chloride)< 0,10*
1,2 – dichlorethylene (ethylene chloride)< 0,10*
Cis-1,2-dichloroethylene< 0,10*
Trans-1,2-dichloroethylene< 0,10*
Benzene< 0,10*
Dichlorobenzene< 0,10*
Dichloromethane< 0,10*
Ethylbenzene< 0,10*
Chlorobenzene< 0,10*
Trichloromethane (Chloroform)< 0,30*
Styrene< 0,10*
Tetrachloretene< 0,10*
Carbon tetrachloride (Carbon tetrachloride)< 0,10*
Toluene< 0,10*
Trichlorobenzene< 0,10*
Trichloretene< 0,10*
Xylene – a combination of isomers< 0,20*
Organochlorinated pesticides and polychlorinated biphenylsSubstanceMethodNanomole
mg/l-1
Alpha-HCH (Hexachlorocyclohexane)< 0,01*
Beta-HCH (Hexachlorocyclohexane)< 0,01*
Gamma-HCH (Hexachlorocyclohexane / Lindane)< 0,01*
Delta-HCCH (hexachlorocyclohexane)< 0,01*
Aldrin< 0,01*
Dieldrin< 0,01*
Endosulfan I< 0,05*
Endosulfan II< 0,05*
Endosulfan Sulfate (Endosulfan Sulfate)< 0,05*
Endrin< 0,05*
Endrinaldehyde< 0,05*
HCB (hexachlorobenzene)< 0,01*
Heptachlor< 0,01*
Heptachlorophoxide trans< 0,01*
Methoxychlor< 0,01*
p,p – DDD (Dichlorodiphenyldichloroethane)< 0,01*
p,p – DDE (Dichlorodiphenyldichloroethylene)< 0,01*
p,p – DDT (dichlorodiphenyltrichloroethane)< 0,01*
Polychlorinated biphenyl (PCB) 28< 0,001*
Polychlorinated biphenyl (PCB) 52< 0,001*
Polychlorinated biphenyl (PCB) 101< 0,001*
Polychlorinated biphenyl (PCB) 118< 0,001*
Polychlorinated biphenyl (PCB) 138< 0,001*
Polychlorinated biphenyl (PCB) 153< 0,001*
Polychlorinated biphenyl (PCB) 180< 0,001*
Non-dissociated componentsSubstanceSubstanceMethodNanomole
mg/l-1mmol/l-1%
Boric acid HBO20,8510,02*12
Silicic acid H2SiO316,80,22*15
OTHER SUBSTANCES
Polycyclic aromatic hydrocarbonsSubstanceMethodNanomole
mg/l-1%
Benzo(а)pyrene< 0,001*
Benzo(b)fluoranthene< 0,001*
Benzo(ghi)perylene< 0,001*
Benzo(k)fluoranthene< 0,001*
Fluoranten0,0012*15
Indeno(1,2,3-c,d)pyrene< 0,001*
Pyrene0,0013*
Part IV.Radioactivity, gases
Radioactive componentsSignSubstanceSubstanceMethodNanomole
mg/l-1Bq/l-1
UranusUVI< 0,0001< 0,002*
Total specific alpha activity0,09*14,6
Total specific beta activity< 0,044*
Total specific beta activity< 0,010
after correction of potassium
Radium 226226Ra0,02*14
Dissolved acid gasesSignSubstanceSubstanceMethodNanomole
mg/l-1ml/l-1
Carbon dioxide free dissolved CO2CO2xxdetermination of content using a Gaertle instrument
Carbon dioxide free dissolved CO2CO2<9<5determination of content using titrimetric analysis (titration)
SulfanH2S<0,005<0,003Hydrogen sulfide VS sampling
Note: Determination of CO22 using a Gaertle instrument due to its small volume is not met.
Dissolved non-acid gasesSignSubstanceSubstanceMethodNanomole
ml/l-1concentration %
HeliumHe0,0050,02*20
HydrogenH2< 0,0023< 0,01*
OxygenO21,014,4*15
NitrogenN25,7525,0*15
ArgonAr0,180,77*20
MethaneCH416,0569,8*20
EthaneC2H6< 0,0023< 0,01*
EthyleneC2H4< 0,0023< 0,01*
PropaneC3H8< 0,0023< 0,01*
ButaneC4H10< 0,0023< 0,01*
IsobutaneC4H10< 0,0023< 0,01*
Total non-acid gas: 23,0 ml / l
PHYSICAL AND PHYSICO-CHEMICAL PARAMETERS OF THE SOURCE
Sampling conditionsUnit of measurementNote
Sampling method: selective:bodový
Air temperature: VS-sampling:7,9°CVS-vzorkování
Atmosphere pressure:1002,7hPaVS-sampling
Physical and physico-chemical parametersValueUnit of measurementMethodNanomole
Source options %%
Efficiency at the time of sampling:90l.min-1
Source temperature during sampling:11,8°CVS-sampling
Density:0,9985kg.l-1*10
Conductivity at 25 ° C:0,381mS.cm-1*5
Conductivity at 20 ° C:0,341mS.cm-1*5
pH at 11,8 °C8,17VS-sampling3
Balance at 180 ° C:223mg.l-1*10
CHSKMn1,0mg.l-1*10
Absorption at 436 nanomoles:< 0,0010*
Absorption at 254 nanomoles:0,0142*15
Redox potential of ORP-206mVVS-sampling
Osmotic pressure:19kPa
Organoleptic and sensory parameters of the source
Colour:transparent, colorless
Smell:light odor oil-giving
Sedimentation:during the fence without sediment
No precipitate appears during storage
Other features: